Preparation, Characterization, and Tetracycline Adsorption Efficiency of Tea Residue-Derived Activated Carbon

Authors

  • Hala A. Faisal Department of Biochemical Engineering / Al-Khwarizmi College of Engineering/ University of Baghdad/ Iraq
  • Alaa Kareem Mohammed Department of Biochemical Engineering / Al-Khwarizmi College of Engineering/ University of Baghdad/ Iraq
  • Nadya Hussin AL Sbani Department of Chemical Engineering/ Faculty of Oil and Gas Engineering/ Al Zawia University/ Libya
  • Wan Nor Roslam Wan Isaha Department of Chemical and Process Engineering/ Faculty of Engineering and Built Environment/ Universiti Kebangsaan Malaysia/ Selangor/ Malaysia

DOI:

https://doi.org/10.22153/kej.2023.09.001

Abstract

The process for preparing activated carbon (AC) made from tea residue was described in this paper. Investigated were the physicochemical characteristics and adsorption efficiency of the produced AC. Activation with potassium hydroxide (KOH) and carbonization at 350 °C are the two key steps in the manufacturing of AC. The activated carbon was used to adsorb Tetracycline (TC). Different parameters were studied at room temperature to show their effects on the adsorption efficiency of TC. These parameters are the initial concentration of adsorbate TC, solution acidity pH, time of adsorption, and adsorbent dosage. The prepared active carbon was characterized using Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), X-ray diffraction (XRD), and Brunauer-Emmett-Teller (BET). The equilibrium of TC adsorption on the tea-activated carbon TAC is effectively represented by the Langmuir model. Tetracycline could be adsorbed onto the prepared activated carbon with a maximum capacity of 45.662 mg g-1. Adsorption kinetics are well represented by pseudo-second-order. The investigation of adsorption thermodynamics demonstrates that TC adsorption on TAC is endothermic and spontaneous

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References

A. A. Mohammed and S. L. Kareem, “Adsorption of tetracycline from wastewater by using Pistachio shell coated with ZnO nanoparticles: Equilibrium, kinetic and isotherm studies,” Alexandria Engineering Journal, vol. 58, no. 3, pp. 917–928, 2019, http://doi: 10.1016/j.aej.2019.08.006.

A. A. Mohammed, T. J. Al-Musawi, S. L. Kareem, M. Zarrabi, and A. M. Al-Ma’abreh, “Simultaneous adsorption of tetracycline, amoxicillin, and ciprofloxacin by pistachio shell powder coated with zinc oxide nanoparticles,” Arabian Journal of Chemistry, vol. 13, no. 3, pp. 4629–4643, 2020, http://doi: 10.1016/j.arabjc.2019.10.010.

F. Yu, S. Sun, S. Han, J. Zheng, and J. Ma, “Adsorption removal of ciprofloxacin by multi-walled carbon nanotubes with different oxygen contents from aqueous solutions,” Chemical Engineering Journal, vol. 285, pp. 588–595, 2016, http://doi: 10.1016/j.cej.2015.10.039.

M. M. Barbooti and S. H. Zahraw, “Removal of amoxicillin from water by adsorption on water treatment residues,” Baghdad Science Journal, vol. 17, no. 3, pp. 1071–1079, 2020, http://doi: 10.21123/BSJ.2020.17.3(SUPPL.).1071.

M. H. Marzbali, M. Esmaieli, H. Abolghasemi, and M. H. Marzbali, “Tetracycline adsorption by H3PO4-activated carbon produced from apricot nut shells: A batch study,” Process Safety and Environmental Protection, vol. 102, pp. 700–709, 2016, http://doi: 10.1016/j.psep.2016.05.025.

K. S. D. Premarathna et al., “Clay-biochar composites for sorptive removal of tetracycline antibiotic in aqueous media,” Journal of Environmental Management, vol. 238, no. January, pp. 315–322, 2019, http://doi: 10.1016/j.jenvman.2019.02.069.

Y. Dai, J. Li, and D. Shan, “Adsorption of tetracycline in aqueous solution by biochar derived from waste Auricularia auricula dregs,” Chemosphere, vol. 238, p. 124432, 2020, http://doi: 10.1016/j.chemosphere.2019.124432.

M. H. Al-Hassani, “Al-Khriet Agricultural Waste Adsorbent, for Removal Lead and Cadmium Ion from Aqueous Solutions,” Al-Khwarizmi Engineering Journal, vol. 9, no. 2, pp. 69–76, 2013.

J. Zhou, F. Ma, and H. Guo, “Adsorption behavior of tetracycline from aqueous solution on ferroferric oxide nanoparticles assisted powdered activated carbon,” Chemical Engineering Journal, vol. 384, no. August, p. 123290, 2020, http://doi: 10.1016/j.cej.2019.123290.

J. Shin et al., “Competitive adsorption of pharmaceuticals in lake water and wastewater effluent by pristine and NaOH-activated biochars from spent coffee wastes: Contribution of hydrophobic and π-π interactions,” Environmental Pollution, vol. 270, p. 116244, 2021, http://doi: 10.1016/j.envpol.2020.116244.

J. Ouyang, L. Zhou, Z. Liu, J. Y. Y. Heng, and W. Chen, “Biomass-derived activated carbons for the removal of pharmaceutical micropollutants from wastewater: A review,” Separation and Purification Technology, vol. 253, no. June, p. 117536, 2020, http://doi: 10.1016/j.seppur.2020.117536.

A. Takdastan et al., “Preparation, characterization, and application of activated carbon from low-cost material for the adsorption of tetracycline antibiotic from aqueous solutions,” Water Science and Technology, vol. 74, no. 10, pp. 2349–2363, 2016, http://doi: 10.2166/wst.2016.402.

A. K. Mohammed, “Modeling of Mass Transfer Transf Coefficient in Rotating Biological Contactor with Perforated Discs ( RPBC ),” Al-Khwarizmi Engineering Journal, vol. 11, no. 4, 2015.

J. Zhou, A. Luo, and Y. Zhao, “Preparation and characterization of activated carbon from waste tea by physical activation using steam,” Journal of the Air and Waste Management Association, vol. 68, no. 12, pp. 1269–1277, 2018, http://doi: 10.1080/10962247.2018.1460282.

J. Tao, X. Fu, C. Du, and D. Zhang, “Tea Residue-Based Activated Carbon: Preparation, Characterization and Adsorption Performance of o-Cresol,” Arabian Journal for Science and Engineering, vol. 46, no. 7, pp. 6243–6258, 2021, http:// http://doi: 10.1007/s13369-020-04968-8.

M. J. Ahmed, “Adsorption of quinolone, tetracycline, and penicillin antibiotics from aqueous solution using activated carbons: Review,” Environmental Toxicology and Pharmacology, vol. 50, pp. 1–10, 2017, doi: 10.1016/j.etap.2017.01.004.

K. E. Talib and S. D. Salman, “Removal of Malachite Green from Aqueous Solution using Ficus Benjamina Activated Carbon-Nonmetal Oxide synthesized by pyro Carbonic Acid Microwave,” Al-Khwarizmi Engineering Journal, vol. 19, no. 2, pp. 26–38, 2023, http://doi: 10.22153/kej.2023.03.002.

F. J. Tuli, A. Hossain, A. K. M. F. Kibria, A. R. M. Tareq, S. M. M. A. Mamun, and A. K. M. A. Ullah, “Removal of methylene blue from water by low-cost activated carbon prepared from tea waste: A study of adsorption isotherm and kinetics,” Environmental Nanotechnology, Monitoring, and Management, vol. 14, no. August, p. 100354, 2020, http://doi: 10.1016/j.enmm.2020.100354.

A. K. Mohammed, A. A. Abdulhassan, and W. Y. Al-meshhdany, “Biosorption of Chromium ions from Solutions by using Date Palm Fibers,” Iraqi Journal of Biotechnology, vol. 16, no. 4, pp. 8–14, 2017.

S. D. Salman, I. M. Rasheed, and A. K. Mohammed, “Adsorption of heavy metal ions using activated carbon derived from Eichhornia (water hyacinth),” in IOP Conference Series: Earth and Environmental Science, 2021, vol. 779, no. 1, http://doi: 10.1088/1755-1315/779/1/012074.

S. D. Salman, I. M. Rasheed, and M. M. Ismaeel, “Removal of diclofenac from aqueous solution on apricot seeds activated carbon synthesized by pyro carbonic acid microwave,” Chemical Data Collections, vol. 43, no. December 2022, p. 100982, 2023, http://doi: 10.1016/j.cdc.2022.100982.

M. Jagtoyen and F. Derbyshire, “Activated carbons from yellow poplar and white oak by H3PO4 activation,” Carbon, vol. 36, no. 7–8, pp. 1085–1097, 1998, http://doi: 10.1016/S0008-6223(98)00082-7.

S. Stankovich, R. D. Piner, S. B. T. Nguyen, and R. S. Ruoff, “Synthesis and exfoliation of isocyanate-treated graphene oxide nanoplatelets,” Carbon, vol. 44, no. 15, pp. 3342–3347, 2006, http://doi: 10.1016/j.carbon.2006.06.004.

H. P. Boehm, “Surface oxides on carbon and their analysis: A critical assessment,” Carbon, vol. 40, no. 2, pp. 145–149, 2002, http://doi: 10.1016/S0008-6223(01)00165-8.

Y. Kan, Q. Yue, D. Li, Y. Wu, and B. Gao, “Preparation and characterization of activated carbons from waste tea by H3PO4 activation in different atmospheres for oxytetracycline removal,” Journal of the Taiwan Institute of Chemical Engineers, vol. 71, pp. 494–500, 2017, http://doi: 10.1016/j.jtice.2016.12.012.

D. T. C. Nguyen, D. V. N. Vo, T. T. Nguyen, T. T. T. Nguyen, L. T. T. Nguyen, and T. Van Tran, “Optimization of tetracycline adsorption onto zeolitic–imidazolate framework-based carbon using response surface methodology,” Surfaces and Interfaces, vol. 28, p. 101549, Feb. 2022, http://doi: 10.1016/J.SURFIN.2021.101549.

H. Zhu, T. Chen, J. Liu, and D. Li, “Adsorption of tetracycline antibiotics from an aqueous solution onto graphene oxide/calcium alginate composite fibers,” RSC Advances, vol. 8, no. 5, pp. 2616–2621, 2018, http://doi: 10.1039/c7ra11964j.

N. M. Jabbar, S. D. Salman, I. M. Rashid, and Y. S. Mahdi, “Removal of an anionic Eosin dye from aqueous solution using modified activated carbon prepared from date palm fronds,” Chemical Data Collections, vol. 42, no. October, p. 100965, 2022, http://doi: 10.1016/j.cdc.2022.100965.

I. M. Rashid, S. D. Salman, A. K. Mohammed, and Y. S. Mahdi, “Green Synthesis of Nickle Oxide Nanoparticles for Adsorption of Dyes,” Sains Malaysiana, vol. 51, no. 2, pp. 533–546, 2022, http://doi: 10.17576/jsm-2022-5102-17.

O. H. Fadhel, M. Y. Eisa, and Z. R. Zair, “Decolorizing of Malachite Green Dye by Adsorption Using Corn Leaves as Adsorbent Material,” Journal of Engineering, vol. 27, no. 2, pp. 1–12, 2021, http://doi: 10.31026/j.eng.2021.02.01.

A. K. Cordova Estrada, F. Cordova Lozano, and R. A. Lara Díaz, “Thermodynamics and Kinetic Studies for the Adsorption Process of Methyl Orange by Magnetic Activated Carbons,” Air, Soil and Water Research, vol. 14, 2021, http://doi: 10.1177/11786221211013336.

H. T. Fan, L. Q. Shi, H. Shen, X. Chen, and K. P. Xie, “Equilibrium, isotherm, kinetic and thermodynamic studies for removal of tetracycline antibiotics by adsorption onto hazelnut shell derived activated carbons from aqueous media,” RSC Advances, vol. 6, no. 111, pp. 109983–109991, 2016, http://doi: 10.1039/c6ra23346e.

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Published

2023-12-01

How to Cite

Preparation, Characterization, and Tetracycline Adsorption Efficiency of Tea Residue-Derived Activated Carbon. (2023). Al-Khwarizmi Engineering Journal, 19(4), 1-15. https://doi.org/10.22153/kej.2023.09.001