Study the Axail Dispersion Model in Ion Exchange Column
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How to Cite

Study the Axail Dispersion Model in Ion Exchange Column. (2009). Al-Khwarizmi Engineering Journal, 5(4), 1-12. https://alkej.uobaghdad.edu.iq/index.php/alkej/article/view/577

Abstract

A mathematical model is developed which predicates the performance of cylindrical ion exchange bed involving comparing of axial dispersion model for cation exchange column with different assumption, this model permits the performance to predicate the residence time within the bed with the variance, axial dispersion and Pecklet No. to indicated deviation from plug flow model.

      Two type of systems are chosen for positive ions first with divalent ions (Ca+2) to exchange with resin of Na+1form used as application in  water softener units and second with monovalent ions (Na+1) to exchange with resin of H+1 form used as application in deionize water units  with two parameters effected in the operation of the two systems different flow rate and different feed concentration by their effect on axial dispersion  in each one where the system are compare from the performance which describe in term of breakthrough time other parameters (the time equivalent to usable capacity "tu" , time equivalent to equilibrium capacity "tt" and length of unused bed "HUNB") are calculated in the operation condition that with axial dispersion are very important in predicated the best condition to operation the cation exchange column as a softener and deionize units.    

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References

[1] Bros A. S. D. and Zola A. S., 'Binary and Ternary Dynamic Cation Exchange NaA'
Universidade Estadual Maringa conference, 2002, Colombo Av/PETROBRAS, Rio de Janero-RJ-Barazil
[2] Crittenden B., Thomas W.J. 'Adsorption Technology &Design' First published Oxford 1998
[3] Wen C. Y. and Fan L. T. 'Model for flow system and Chemical Reaction' Marcel Dkker NewYork1975
[4] Cooney D.O. 'Column Configuration and Performance in Fixed bed Ion Exchange', I&E C Vol6,No.1 February 1967
[5] Diaion,®' Manual of Ion Exchange Resin and Synthetic Adsorption, part1, Mitsubishi Chemical Corporation(Data sheet 1995)
[6] Duncknorst F. T.and Houghton G. 'Digital Computer Simulation of non-liner Equilibrium Chromatography with Axial Dispersion', I&EC Fundamental, Vol.5, No.1 February 1966
[7] Charles G., Hill JR 'An Introduction to Chemical Engineering Kinetics Reactor Design 'John Willy&Son Inc, USA, 1977
[8] Duong H.M. and Shallcross D. C., 'Modeling of Radial-Flow- Ion Exchange Bed Performance', Ind. Eng. Chem. Res. 2005,44, 3681-3691
[9] Duong H.M. and Shallcross D. C.,' Ion Exchange Column Performance Model Intra-Particle and Solution, Ind. Eng. Chem. Res.,2002,49.
[10] Fogler H. S. 'Elements of Chemical reaction Engineering', Prentice-Hall-Inc. New Jersey. 1986
[11] Abu-Reesh I. M. and Abu-Sharkh B. F. 'Comparison of Axial Dispersion and Tank-in-Series Models for Simulating the Performance of Enzyme Reactor' Ind. Eng. Res. 2003, 42, 5495-5505
[12] Regal J.A. Hand Book of Industrial Chemistry, 8th Edition New York, Vannastrr and Richolid Company, Inc,1983
[13] Calson and Richardson 'Chemical Engineering Volume2 ' Fifth Edition ,India 2002
[14] Wikes J.O. and LaValle P. 'Fixed and Fluidized Bed Ion Exchange 'University of Michigan ChE360 Laboratory 12-2002, www.ChE360 Laboratory
[15] Mathd M. 'Ion Exchange in Analytical Chemistry' Academic/PRACU 1982
[16] levenspiel O. 'Chemical Reaction Engineering 'contain (Ind. Eng. Chem.1958, Ind. Eng. Chem. 1957, Ind. Eng. Chem. 1961),Third Edition ,John Wiley&Son,1999
[17] Perry R. H. , Chiltion C.H. 'Chemical Engineering Hand Book' Six Edition, McGraw-Hill Company1997
[18] Shinnar R. 'Use of Residence and Contact Time Distribution in Reactor Design' in Chemical Reaction and Reactor Engineering,Carberry,NewYork,1987
[19] Scoop R. 'Slow Piratical Diffusion Ion Exchange Column', I&EC Fundamental Vol. 4,No.30 August 1956
[20] Ofoli R. Y. A. and Komolprasert V. 'Dispersion Model for Predicating the Extent of Starch Liquefaction', Biotechnol-BioEgn., 1991, 37 ,681-690
[21] Qasim S. R., Motly E. M. and Zhu G., 'Water Works Engineering', Prentic-Hall of India, 2006
[22] Maccabe W., Smith J. C. and Harriott P., 'Unit Operation Of Chemical Engineering' Seven Edition, Chemical Engineering Series McCrow-Hill, 2005
[23] Tsaur Y. and Shallcross D. C., 'Molding of Ion Exchange Performance in Fixed Radial Flow Annular Bed', Ind. Eng. Chem. Res. 1997, 36, 2359-2367

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