استثمار الرماد المتطاير المعالج في تصنيع متراكب نانوي Fe3O4@FA@GO@BiOCl فعال ضوئيًا لإزالة الأصباغ من المحاليل المائية
DOI:
https://doi.org/10.22153/kej.2026.03.003الكلمات المفتاحية:
Fe3O4@FA@GO@BiOCl; visible light photocatalysis; fly ash; methyl orange degradation; core/shell heterojunction; magnetic nanocomposite; advanced oxidation processes (AOPs); wastewater treatmentالملخص
الملخّصتم تطوير محفّز ضوئي مستدام وقابل للفصل مغناطيسيًا من نوع Fe3O4@FA@GO@BiOC، وتقييم أدائه في إزالة صبغة الميثيل أورنج (MO) تحت الإشعاع المرئي. استُخدم الرماد المتطاير المعالج (FA)، المستعاد من مخلفات محطات توليد الطاقة، كداعم مسامي منخفض الكلفة يسهّل تركيز الملوثات ويعزز توزيع المكوّنات النشطة. أسهمت أكسدة الغرافين (GO) في تحسين انتقال الشحنات بين الواجهات، بينما وفّر مركب BiOCl استجابة فعّالة للضوء المرئي، وضمن Fe3O4 إمكانية الفصل المغناطيسي السريع للمحفّز بعد الاستخدام.
تم تأكيد الخصائص التركيبية والمورفولوجية والبصرية والسطحية والمغناطيسية للمحفّز باستخدام تقنيات XRD وFE-SEM وTEM وUV–Vis DRS وBET وVSM، والتي بيّنت تكوّن بنية لب/ القشرة ذات مساحة سطحية عالية وصفات مغناطيسية مرنة. تمت دراسة تأثير جرعة المحفّز وتركيز الصبغة الابتدائي ودرجة الحموضة (pH) وإضافة H₂O₂ على كفاءة الإزالة. أظهر المتراكب Fe3O4@FA@GO@BiOCl كفاءة عالية، إذ حقق إزالة كاملة للصبغة خلال 45 دقيقة، متبعًا معادلة حركية شبه من الدرجة الأولى متفوقًا على المركبين Fe₃O₄@FA و Fe3O4@FA@GO وحقق تمعدن كلي للصبغة بلغ 92.4% قيمة الكربون العضوي الكلي (TOC) خلال 90 دقيقة من الإشعاع، مما يشير إلى تحلّل المركبات الأروماتية الوسيطة وليس امتصاصها فقط. كما حافظ المتراكب على استقراريته البنيوية وقدرته على الفصل المغناطيسي عبر ثلاث دورات تشغيل متتالية. توضح هذه النتائج أنّ دمج الرماد المتطاير المعالج مع مواد نانوية فعّالة ضوئيًا يوفّر نهجًا واعدًا لمعالجة مياه الصرف وتصميم محفّزات منخفضة الكلفة ضمن الإطار الاقتصادي.
التنزيلات
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