الملخص
The ability to inhibit corrosion of low carbon steel in a salt solution (3.5%NaCl) has been checked with three real expired drugs (Cloxacillin, Amoxicillin, Ceflaxin) with variable concentrations (0, 250, 500, 750) mg/L were examined in the weight loss. The inhibition efficiency of the Cloxacillin 750 mg/L showed the highest value (82.8125 %) and the best inhibitor of the rest of the antibiotics. The different concentrations of Cloxacillin drug (0, 250, 500, 750) mg/L and temperature (25, 35, 45, 55) oC were studied as variables with potentiodynamic polarization, Scanning Electron Microscopy (SEM) for surface morphology and electrochemical impedance spectroscopy (EIS) depending on current values and the resistance of charge to calculate the inhibition efficiency. The main observations of these tests were that polarization curves showed a mixed-type inhibition of expired Cloxacillin. The inhibition efficiency increased with increasing Cloxacillin concentration but not with increasing temperature.
المراجع
A. S. Fouda, M. A. El Morsi, and T. El Mogy, “Studies on the inhibition of carbon steel corrosion in hydrochloric acid solution by expired carvedilol drug,” Green Chem. Lett. Rev., vol. 10, no. 4, pp. 336–345, 2017, doi: 10.1080/17518253.2017.1380236.
M. Alfakeer, M. Abdallah, and A. Fawzy, “Corrosion inhibition effect of expired ampicillin and flucloxacillin drugs for mild steel in aqueous acidic medium,” Int. J. Electrochem. Sci., vol. 15, no. 4, pp. 3283–3297, 2020, doi: 10.20964/2020.04.09.
S. Acharya and S. N. Upadhyay, “The inhibition of corrosion of mild steel by some fluoroquinolones in sodium chloride solution,” Transactions of the Indian Institute of Metals, 2004. https://www.researchgate.net/publication/43526805_The_inhibition_of_corrosion_of_mild_steel_by_some_fluoroquinolones_in_sodium_chloride_solution (accessed Apr. 10, 2021).
Z. Saleem et al., “WHO key access antibiotics price, availability and affordability in private sector pharmacies in Pakistan,” Cost Eff. Resour. Alloc., vol. 19, no. 1, pp. 1–10, 2021, doi: 10.1186/s12962-021-00263-x.
M. H. O. Ahmed, A. A. Al-Amiery, Y. K. Al-Majedy, A. A. H. Kadhum, A. B. Mohamad, and T. S. Gaaz, “Synthesis and characterization of a novel organic corrosion inhibitor for mild steel in 1 M hydrochloric acid,” Results Phys., vol. 8, pp. 728–733, 2018, doi: 10.1016/j.rinp.2017.12.039.
B. Se, Encyclopedia of Applied Electrochemistry. 2014.
M. Grossi and B. Riccò, “Electrical impedance spectroscopy (EIS) for biological analysis and food characterization: A review,” J. Sensors Sens. Syst., vol. 6, no. 2, pp. 303–325, 2017, doi: 10.5194/jsss-6-303-2017.
C. Torres, R. Johnsen, and M. Iannuzzi, “Crevice corrosion of solution annealed 25Cr duplex stainless steels: Effect of W on critical temperatures,” Corros. Sci., vol. 178, p. 109053, Jan. 2021, doi: 10.1016/J.CORSCI.2020.109053.
D. G. J. Larsson, “Antibiotics in the environment,” https://mc.manuscriptcentral.com/ujms, vol. 119, no. 2, pp. 108–112, 2014, doi: 10.3109/03009734.2014.896438.
M. Ash and I. Ash, Handbook of Corrosion inhibitors, vol. 98, no. 10. 2000.
M. STERN, “Surface Area Relationships In Polarization and Corrosion,” Corrosion, vol. 14, no. 7, pp. 43–46, Jul. 1958, doi: 10.5006/0010-9312-14.7.43.
W. Zhou, R. Apkarian, Z. L. Wang, and D. Joy, “Fundamentals of Scanning Electron Microscopy (SEM),” Scanning Microsc. Nanotechnol. Tech. Appl., pp. 1–40, 2006, doi: 10.1007/978-0-387-39620-0_1.
K. M. Emran, S. M. Ali, and H. A. Al Lehaibi, “Green Methods for Corrosion Control,” Corros. Inhib. Princ. Recent Appl., Dec. 2017, doi: 10.5772/INTECHOPEN.72762.
M. Azzi and J. A. Szpunar, “Tribo-electrochemical technique for studying tribocorrosion behavior of biomaterials,” Biomol. Eng., vol. 24, no. 5, pp. 443–446, 2007, doi: 10.1016/j.bioeng.2007.07.015.
M. Zunita, D. Wahyuningrum, Buchari, B. Bundjali, I. G. Wenten, and R. Boopathy, “Corrosion inhibition performances of imidazole derivatives-based new ionic liquids on carbon steel in brackish water,” Appl. Sci., vol. 10, no. 20, pp. 1–14, 2020, doi: 10.3390/app10207069.
J. Imanipoor, M. Mohammadi, M. Dinari, and M. R. Ehsani, “Adsorption and Desorption of Amoxicillin Antibiotic from Water Matrices Using an Effective and Recyclable MIL-53(Al) Metal-Organic Framework Adsorbent,” J. Chem. Eng. Data, vol. 66, no. 1, pp. 389–403, 2021, doi: 10.1021/acs.jced.0c00736.
M. W. S. Jawich, G. A. Oweimreen, and S. A. Ali, “Heptadecyl-tailed mono- and bis-imidazolines: A study of the newly synthesized compounds on the inhibition of mild steel corrosion in a carbon dioxide-saturated saline medium,” Corros. Sci., vol. 65, pp. 104–112, 2012, doi: 10.1016/j.corsci.2012.08.001.
A. G. Fernández and L. F. Cabeza, “Anodic Protection Assessment Using Alumina-Forming Alloys in Chloride Molten Salt for CSP Plants,” Coatings 2020, Vol. 10, Page 138, vol. 10, no. 2, p. 138, Feb. 2020, doi: 10.3390/COATINGS10020138.
A. Singh, K. R. Ansari, M. A. Quraishi, and H. Lgaz, “Effect of Electron Donating Functional Groups on Corrosion Inhibition of J55 Steel in a Sweet Corrosive Environment: Experimental, Density Functional Theory, and Molecular Dynamic Simulation,” Mater. 2019, Vol. 12, Page 17, vol. 12, no. 1, p. 17, Dec. 2018, doi: 10.3390/MA12010017.
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